A mononuclear manganese(III) complex of an asymmetric macrocyclic ligand with a ring contraction [MnHL2(ClO4)](ClO4)•2.5H2O

被引：8

作者：

Qian, M

Gou, SH ^{[1
]}

Ju, HX

Huang, W

Duan, CY

You, XZ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2000年 / 25卷 / 05期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1023/A:1007050902958

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The template reaction of sodium 2,6-diformyl-4-chlorophenolate and N,N-bis(2-aminoethyl)-hydroxyethylamine followed by in situ transmetallation of Mn(ClO4)(2) results in a mononuclear manganese(III) complex of one 21-membered asymmetric 2:2 Schiff base macrocycle, in which a hydroxyethyl group of the amine has been eliminated and ring contraction at one chamber of the macrocycle has occurred to form an imidazolidine ring. An X-ray study indicates that the geometry about the manganese(III) ion is distorted octahedral. The electrochemical behavior of this complex in MeCN has been studied by cyclic voltammetry.

引用

页码：584 / 588

页数：5

共 15 条

[1] PREPARATION, X-RAY AND SPECTROSCOPIC INVESTIGATIONS OF EUROPIUM(III) TRINITRATO COMPLEXES WITH THE MACROCYCLE DERIVED FROM 2,6-DIFORMYL-4-CHLOROPHENOL AND DIETHYLENETRIAMINE [J].