Transition-metal-catalyzed imine metathesis

被引：59

作者：

Cantrell, GK ^{[1
]}

Meyer, TY ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 25期

关键词：

D O I：

10.1021/om9708889

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixtures of (n-Pr)N=CHPh (3) and PhN=CH(t-Bu) (4) undergo catalytic metathesis in the presence of 4 mol % of (DME)Cl2Mo(=NR)(2) (R=t-Bu (la), 2,6-diisopropylphenyl (2)) at 85-90 degrees C in C6D6 to form 1:1:1:1 equilibrium mixtures with PhN=CHPh (5) and (n-Pr)N=CH(t-Bu) (6).

引用

页码：5381 / 5383

页数：3

共 24 条

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