Scalable production of graphene sheets by mechanical delamination

被引：236

作者：

Knieke, Catharina ^{[1
]}

Berger, Angela ^{[1
]}

Voigt, Michael ^{[1
]}

Taylor, Robin N. Klupp ^{[1
]}

Roehrl, Jonas ^{[2
]}

Peukert, Wolfgang ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Particle Technol, D-91058 Erlangen, Germany

[2] Univ Erlangen Nurnberg, Inst Tech Phys, D-91058 Erlangen, Germany

来源：

CARBON | 2010年 / 48卷 / 11期

关键词：

STIRRED MEDIA MILLS; SODIUM DODECYL-SULFATE; STRESS INTENSITY; GRAPHITE; EXFOLIATION; ENERGY; REDUCTION; PARTICLES;

D O I：

10.1016/j.carbon.2010.05.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mono- and multilayer graphene sheets have been successfully produced from commercial graphite powder in a wet grinding process under mild milling conditions. The shear forces in the milling chamber lead to a continuous delamination of ultrathin graphene flakes which are dispersed in a liquid medium. To avoid agglomeration of the exfoliated flakes the anionic surfactant sodium dodecyl sulfate was used. By adjusting the process parameters in a way to overcome the weak interlayer forces between the sheets without breaking them leads to the fabrication of thin flakes with high aspect ratios. The presented scalable process allows a high-yield and low-cost production of free-standing graphene sheets for various applications. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：3196 / 3204

页数：9

共 39 条

[1] Low energy pure shear milling: A method for the preparation of graphite nano-sheets [J].

Antisari, M. Vittori ;

Montone, A. ;

Jovic, N. ;

Piscopiello, E. ;

Alvani, C. ;

Pilloni, L. .

SCRIPTA MATERIALIA, 2006, 55 (11) :1047-1050

[2] Stress intensity in stirred media mills and its effect on specific energy requirement [J].

Becker, M ;

Kwade, A ;

Schwedes, J .

INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2001, 61 (03) :189-208

[3] Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics [J].

Berger, C ;

Song, ZM ;

Li, TB ;

Li, XB ;

Ogbazghi, AY ;

Feng, R ;

Dai, ZT ;

Marchenkov, AN ;

Conrad, EH ;

First, PN ;

de Heer, WA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (52) :19912-19916

[4] Electronic confinement and coherence in patterned epitaxial graphene [J].

Berger, Claire ;

Song, Zhimin ;

Li, Xuebin ;

Wu, Xiaosong ;

Brown, Nate ;

Naud, Cecile ;

Mayou, Didier ;

Li, Tianbo ;

Hass, Joanna ;

Marchenkov, Atexei N. ;

Conrad, Edward H. ;

First, Phillip N. ;

de Heer, Wait A. .

SCIENCE, 2006, 312 (5777) :1191-1196

[5] Estimation of Stresses Required for Exfoliation of Clay Particles in Polymer Nanocomposites [J].

Borse, Nitin K. ;

Kamal, Musa R. .

POLYMER ENGINEERING AND SCIENCE, 2009, 49 (04) :641-650

[6] Raman spectroscopy of graphene on different substrates and influence of defects [J].

Das, Anindya ;

Chakraborty, Biswanath ;

Sood, A. K. .

BULLETIN OF MATERIALS SCIENCE, 2008, 31 (03) :579-584

[7]

DRZMALA J, 1994, ADV COLLOID INTERFAC, V50, P143

[8] Graphene-based Composite Thin Films for Electronics [J].

Eda, Goki ;

Chhowalla, Manish .

NANO LETTERS, 2009, 9 (02) :814-818

[9]

ENGLERT JM, 2009, ADV MATER, V21, P1

[10] Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

← 1 2 3 4 →