Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway

被引：169

作者：

Vallee, Frederic ^{[1
]}

Mousseau, James J. ^{[1
]}

Charette, Andre B. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 05期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

CROSS-COUPLING REACTIONS; C-H BONDS; HETEROAROMATIC-COMPOUNDS; UNACTIVATED ARENES; SELF-ORGANIZATION; POLYMERIZATION; HETEROCYCLES; ACTIVATION; REAGENTS; CLEAVAGE;

D O I：

10.1021/ja910687u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general and efficient iron-catalyzed direct arylation of benzene and hetereoaryl derivatives using a cost-effective and environmentally benign catalyst is described. The reaction is performed under neat conditions and can proceed at room temperature.

引用

页码：1514 / +

页数：4

共 44 条

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