Competitive oxidation of 1- and 2-propanol catalyzed by titanium silicalite-1 and the application for selective oxidation of 1-methoxy-2-propanol to 1-methoxy-2-propanone

被引：14

作者：

Hayashi, H ^{[1
]}

Kikawa, K ^{[1
]}

Murai, Y ^{[1
]}

Shigemoto, N ^{[1
]}

Sugiyama, S ^{[1
]}

Kawashioro, K ^{[1
]}

机构：

[1] SHIKOKU RES INST INC,DIV CHEM,TAKAMATSU,KAGAWA 76101,JAPAN

来源：

CATALYSIS LETTERS | 1996年 / 36卷 / 1-2期

关键词：

TS-1; competitive oxidation; 1-; and; 2-propanol; 1-methoxy-2-propanol;

D O I：

10.1007/BF00807212

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidation of 2-propanol with hydrogen peroxide catalyzed by TS-1 was strongly retarded in the presence of an equimolar 1-propanol to a level of 1-propanol oxidation, and the competitive oxidation behavior was applied for the selective oxidation of 1-methoxy-2-propanol to afford 1-methoxy-2-propanone in a high yield of 85%.

引用

页码：99 / 102

页数：4