Synthesis of biaryl P,N ligands by novel palladium-catalyzed phosphination using triarylphosphines:: Catalytic application of C-P activation

被引：79

作者：

Kwong, FY ^{[1
]}

Chan, KS ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 11期

关键词：

D O I：

10.1021/om9909338

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first application of palladium-catalyzed phosphination using tertiary phosphines as the diarylphosphinating agents for the synthesis of biaryl P,N Ligands from their corresponding O,N triflates was reported.

引用

页码：2058 / 2060

页数：3

共 28 条

[1] Convenient and direct preparation of tertiary phosphines via nickel-catalysed cross-coupling [J].

Ager, DJ ;

East, MB ;

Eisenstadt, A ;

Laneman, SA .

CHEMICAL COMMUNICATIONS, 1997, (24) :2359-2360

[2]

ALOCK NW, 1993, TETRAHEDRON-ASYMMETR, V4, P743

[3] RATES AND MECHANISMS OF OXIDATIVE ADDITION TO ZEROVALENT PALLADIUM COMPLEXES GENERATED IN-SITU FROM MIXTURES OF PD0(DBA)2 AND TRIPHENYLPHOSPHINE [J].

AMATORE, C ;

JUTAND, A ;

KHALIL, F ;

MBARKI, MA ;

MOTTIER, L .

ORGANOMETALLICS, 1993, 12 (08) :3168-3178

[4] EVIDENCE OF THE FORMATION OF ZEROVALENT PALLADIUM FROM PD(OAC)2 AND TRIPHENYLPHOSPHINE [J].

AMATORE, C ;

JUTAND, A ;

MBARKI, MA .

ORGANOMETALLICS, 1992, 11 (09) :3009-3013

[5] Novel concepts in directed biaryl synthesis - Part 69 - Palladium-mediated intramolecular acylation reaction in the attempted phosphinylation of a sterically hindered trifluoromethylsulfonyloxybiaryl carboxylic ester [J].

Bringmann, G ;

Wuzik, A ;

Vedder, C ;

Pfeiffer, M ;

Stalke, D .

CHEMICAL COMMUNICATIONS, 1998, (11) :1211-1212

[6] SYNTHESIS OF CHIRAL 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP) VIA A NOVEL NICKEL-CATALYZED PHOSPHINE INSERTION [J].

CAI, DW ;

PAYACK, JF ;

BENDER, DR ;

HUGHES, DL ;

VERHOEVEN, TR ;

REIDER, PJ .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (23) :7180-7181

[7]

Ding KL, 1999, CHEM-EUR J, V5, P1734, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1734::AID-CHEM1734>3.3.CO

[8]

2-7

[9] A bis-steroidal phosphine as new chiral hydrogenation ligand [J].

Enev, V ;

Ewers, CLJ ;

Harre, M ;

Nickisch, K ;

Mohr, JT .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (21) :7092-7093

[10] Mechanistic studies on the aryl-aryl interchange reaction of ArPdL2I (L = triarylphosphine) complexes [J].

Goodson, FE ;

Wallow, TI ;

Novak, BM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) :12441-12453

← 1 2 3 →