Novel concepts in directed biaryl synthesis - Part 69 - Palladium-mediated intramolecular acylation reaction in the attempted phosphinylation of a sterically hindered trifluoromethylsulfonyloxybiaryl carboxylic ester

被引:13
作者
Bringmann, G
Wuzik, A
Vedder, C
Pfeiffer, M
Stalke, D
机构
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
关键词
D O I
10.1039/a801674g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The unexpected palladium-assisted cyclization reaction of a sterically hindered o-methoxycarbonyl-o'-trifluoromethylsulfonyloxybiaryl gives fluorenone 4, via intramolecular acylation instead of the attempted phosphinylation.
引用
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页码:1211 / 1212
页数:2
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