Crystal structure of the mononuclear complex [Mn(mesalim)2Cl] and electrochemical studies of manganese complexes of the ligand Hmesalim

被引：5

作者：

Godbole, MD

Grigiotti, E

Zanello, P

Mills, AM

Spek, AL

Bouwman, E

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Siena, Dipartimento Chim, I-53100 Siena, Italy

[3] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3508 TC Utrecht, Netherlands

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 01期

关键词：

manganese complexes; oxidation catalysis; electrochemistry; crystal structures;

D O I：

10.1016/j.ica.2004.08.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Mn(mesalim)(2)Cl] (1), (Hmesalim = methyl salicylimidate) has been synthesized and fully characterized. The manganese(III) complex is formed by the reaction of the ligand Hmesalim with manganese(II) chloride. Complex 1 is mononuclear and crystallizes in the space group P (1) over bar. Electrochemical studies were performed for complex 1, as well as for the related complexes [Mn(mesalim)(2)(OAc)(MeOH] . MeOH (2) and [Mn-2(etsalim)(4)(Hetsalim)(2)](ClO4)(2) (3), (Hetsalim = ethyl salicylimidate). The complexes display intricate oxidation-reduction behaviour, and coulometric analyses in combination with electrochemical analyses have been used to understand the electron transfer mechanisms occurring at the electrodes. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：233 / 238

页数：6

共 16 条

[1] SYNTHETIC STUDIES RELATED TO MYCOBACTINS .1. SYNTHESIS OF 2-(2'-HYDROXYPHENYL)-2-OXAZOLINE-4-CARBOXYLIC ACID AND RELATED COMPOUNDS [J].