Roles of polymer ligands in nanoparticle stabilization

被引：190

作者：

Grubbs, Robert B. ^{[1
]}

机构：

[1] Dartmouth Coll, Dept Chem, Hanover, NH 03755 USA

[2] Dartmouth Coll, Ctr Nanomat Res, Hanover, NH 03755 USA

来源：

POLYMER REVIEWS | 2007年 / 47卷 / 02期

关键词：

nanoparticles; polymer ligands; catalysis; TRANSFER RADICAL POLYMERIZATION; MODIFIED GOLD NANOPARTICLES; BLOCK-COPOLYMER MICELLES; TRANSITION-METAL NANOPARTICLES; PLACE-EXCHANGE-REACTIONS; ORGANOMETALLIC POLYMERS; MAGNETIC NANOPARTICLES; NANOCLUSTER FORMATION; COBALT NANOPARTICLES; HYBRID NANOPARTICLES;

D O I：

10.1080/15583720701271245

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Both inorganic nanoparticles and polymers have become ubiquitous components Of nanostructured systems. The development of an understanding of the interactions between these components will be of crucial importance in the further elaboration of these systems. This review touches upon two aspects of control over surface chemistry in inorganic nanoparticles with polymer ligands: (1) the effect of polymer ligands on accessibility of the inorganic nanoparticle surface to other species, such as is necessary in catalysis; and (2) the design of polymer ligands that can be modified to enable compatibility of the entire polymer-coated nanoparticle with a broad variety of other materials.

引用

页码：197 / 215

页数：19

共 191 条

[1] Selective growth of cobalt nanoclusters in domains of block copolymer films [J].