Stabilization of (trialkylphosphine)ruthenium alkylidene metathesis catalysts using phosphine exchange

被引：13

作者：

Bolton, Sarah L. ^{[1
]}

Williams, Joseph E. ^{[1
]}

Sponsler, Michael B. ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 10期

关键词：

D O I：

10.1021/om061098e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The second-generation Grubbs analogues (H(2)IMes)RuCl2(=CHPh)(PR3) (R = Me, Bu) were essentially metathesis-inactive and air-stable at room temperature but exhibited first-order metathesis with ethyl vinyl ether at elevated temperature. The PMe3 complex underwent second-order ligand exchange with PBu3, indicating different coordination mechanisms (dissociative vs associative) in the two reactions.

引用

页码：2485 / 2487

页数：3