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Catalysis in ionic liquids

被引：2000
作者：
Parvulescu, Vasile I.
Hardacre, Christopher
机构：
[1] Univ Bucharest, Dept Chem Technol & Catalysis, Bucharest 030016, Romania
[2] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland
来源：
CHEMICAL REVIEWS | 2007年 / 107卷 / 06期
关键词：
D O I：
10.1021/cr050948h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A review in the use of ionic liquids' solvents in catalyzed reactions as well as its use in biocatalytic and electrocatalyzed reactions has been presented. These reactions include hydrogenation, catalytic oxidation, acid-base-catalyzed reactions, carbonylation and hydroformylation, dimerization, polymerization, Heck reaction, Suzuki cross-coupling and other related reaction. The study clearly shows a large potential using the combination of ILs and solid catalysts in both liquid-phase and gas-phase reactions. The latter shows the versatility of ILs in stabilizing homogeneous catalysts and enables good mass transport of gas reagents using thin films of the ionic liquid.
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收藏
页码：2615 / 2665
页数：51
相关论文
共 551 条
  • [1] Quaternary ammonium zinc- or tin-containing ionic liquids: water insensitive, recyclable catalysts for Diels-Alder reactions
    Abbott, AP
    Capper, G
    Davies, DL
    Rasheed, RH
    Tambyrajah, V
    [J]. GREEN CHEMISTRY, 2002, 4 (01) : 24 - 26
  • [2] Supported choline hydroxide (ionic liquid) as heterogeneous catalyst for aldol condensation reactions
    Abelló, S
    Medina, F
    Rodríguez, X
    Cesteros, Y
    Salagre, P
    Sueiras, JE
    Tichit, D
    Coq, B
    [J]. CHEMICAL COMMUNICATIONS, 2004, (09) : 1096 - 1097
  • [3] The synthesis of mesoporous materials using novel ionic liquid templates in water
    Adams, CJ
    Bradley, AE
    Seddon, KR
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 2001, 54 (11) : 679 - 681
  • [4] Stereoselective hydrogenation reactions in chloroaluminate(III) ionic liquids: a new method for the reduction of aromatic compounds
    Adams, CJ
    Earle, MJ
    Seddon, KR
    [J]. CHEMICAL COMMUNICATIONS, 1999, (11) : 1043 - 1044
  • [5] Adams CJ, 1998, CHEM COMMUN, P2097
  • [6] Polyoxoanion- and tetrabutylammonium-stabilized Rh(0)n nanoclusters:: Unprecedented nanocluster catalytic lifetime in solution
    Aiken, JD
    Finke, RG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (38) : 8803 - 8810
  • [7] Mannich-type reaction promoted by an ionic liquid
    Akiyama, T
    Suzuki, A
    Fuchibe, K
    [J]. SYNLETT, 2005, (06) : 1024 - 1026
  • [8] Sulfonylation reactions of aromatics using FeCl3-based ionic liquids
    Alexander, MV
    Khandekar, AC
    Samant, SD
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 223 (1-2) : 75 - 83
  • [9] A mechanistic study of the electro-oxidation of bromide in acetonitrile and the room temperature ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at platinum electrodes
    Allen, GD
    Buzzeo, MC
    Villagrán, C
    Hardacre, C
    Compton, RG
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 575 (02) : 311 - 320
  • [10] A comparative study on the reactivity of electrogenerated bromine with cyclohexene in acetonitrile and the room temperature ionic liquid, 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide
    Allen, GD
    Buzzeo, MC
    Davies, LG
    Villagrán, C
    Hardacre, C
    Compton, RG
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (41) : 16322 - 16327
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