Catalysis in ionic liquids

被引:2000
作者
Parvulescu, Vasile I.
Hardacre, Christopher
机构
[1] Univ Bucharest, Dept Chem Technol & Catalysis, Bucharest 030016, Romania
[2] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Ctr, Belfast BT9 5AG, Antrim, North Ireland
关键词
D O I
10.1021/cr050948h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A review in the use of ionic liquids' solvents in catalyzed reactions as well as its use in biocatalytic and electrocatalyzed reactions has been presented. These reactions include hydrogenation, catalytic oxidation, acid-base-catalyzed reactions, carbonylation and hydroformylation, dimerization, polymerization, Heck reaction, Suzuki cross-coupling and other related reaction. The study clearly shows a large potential using the combination of ILs and solid catalysts in both liquid-phase and gas-phase reactions. The latter shows the versatility of ILs in stabilizing homogeneous catalysts and enables good mass transport of gas reagents using thin films of the ionic liquid.
引用
收藏
页码:2615 / 2665
页数:51
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