Structures of thermally and chemically reduced graphene

被引:139
作者
Ju, Hye-Mi [1 ]
Huh, Seung Hun [1 ]
Choi, Seong-Ho [1 ]
Lee, Hong-Lim [2 ]
机构
[1] KICET, Nanotechnol Convergence Lab, Seoul 153801, South Korea
[2] Yonsei Univ, Adv Mat Engn, Seoul 120749, South Korea
关键词
Graphene; Graphene oxide; Reduction; Structure; GRAPHITE; DISPERSIONS; STABILITY;
D O I
10.1016/j.matlet.2009.11.016
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study investigated the structures and compositions of two types of graphene (GP) produced by the reduction of graphene oxide (GO): GP(TR). produced by thermal reduction at 1073 K in N-2; and GP(CR). chemically reduced with hyrdazine. GP(TR) and GP(CR) have a small number of surface oxide groups with the compositions C100O3+/-1 and C100O6.5+/-2 and consist of six layers and three layers, respectively. The interlayer spaces are slightly larger than those in typical graphene produced by "top-down" exfoliation from graphite. These structures and compositions are intrinsic properties of graphene produced by the "bottom-up" layer-by-layer stacking process. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:357 / 360
页数:4
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