Formation of dissymmetric eight-membered silalketals by ring-closing metathesis and their conversion to spiroketals

被引：25

作者：

Boiteau, JG ^{[1
]}

Van de Weghe, P ^{[1
]}

Eustache, J ^{[1
]}

机构：

[1] Univ Haute Alsace, CNRS, Lab Synthese Organ & Chim Microbienne, Ecole Natl Super Chim Mulhouse, F-68093 Mulhouse, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)01929-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Eight-membered unsymmetrical silalketals are formed by RCM of mixed allyl/homoallyl silalketals. They are crucial intermediates in a short synthetic sequence to spiroketals illustrated in this paper by the synthesis of the C-28-C-38 portion of okadaic acid. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：239 / 242

页数：4

共 15 条

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