Thermal treatment-dependent chemical composition of ternary CdS1-xSex nanocrystals grown in borosilicate glass

被引:28
作者
Azhniuk, Yu. M. [1 ]
Gomonnai, A. V. [1 ]
Hutych, Yu. I. [1 ]
Lopushansky, V. V. [1 ]
Turok, I. I. [1 ]
Yukhymchuk, V. O. [2 ]
Zahn, D. R. T. [3 ]
机构
[1] Ukr Nat Acad Sci, Inst Electron Phys, UA-88017 Uzhgorod, Ukraine
[2] Ukr Nat Acad Sci, V Lashkaryov Inst Semicond Phys, UA-03028 Kiev, Ukraine
[3] Tech Univ Chemnitz, D-09107 Chemnitz, Germany
关键词
Nanomaterials; Semiconducting cadmium compounds; Semiconducting ternary compounds; CDSE/CDS CORE/SHELL NANOCRYSTALS; ANGLE X-RAY; RESONANT RAMAN; SURFACE PHONONS; QUANTUM DOTS; SIZE; NANOPARTICLES; CDS; CONFINEMENT; SCATTERING;
D O I
10.1016/j.jcrysgro.2010.02.033
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Variation of the chemical composition of ternary CdS1-xSex nanocrystals grown in borosilicate glass depending on the thermal treatment is studied by resonant Raman spectroscopy. It is shown that only for the nanocrystals with roughly equal content of substitutive S and Se chalcogen atoms (0.4 < x < 0.6) the nanocrystal composition is independent of the thermal treatment parameters. In other cases an increase of the thermal treatment temperature (625-700 degrees C) and duration (2-12 h) results in a considerable increase of the predominant chalcogen content in the nanocrystals. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1709 / 1716
页数:8
相关论文
共 46 条
[1]   Raman spectroscopy of optical phonon confinement in nanostructured materials [J].
Arora, Akhilesh K. ;
Rajalakshmi, M. ;
Ravindran, T. R. ;
Sivasubramanian, V. .
JOURNAL OF RAMAN SPECTROSCOPY, 2007, 38 (06) :604-617
[2]   Evidence for formation of Se molecular clusters during precipitation of CdSe1-x S x nanoparticles in glass [J].
Azhniuk, Y. M. ;
Gomonnai, A. V. ;
Hutych, Y. I. ;
Lopushansky, V. V. ;
Prots, L. A. ;
Turok, I. I. ;
Zahn, D. R. T. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2009, 95 (02) :473-477
[3]   Resonant Raman studies of compositional and size dispersion of CdS1-xSex nanocrystals in a glass matrix [J].
Azhniuk, YM ;
Milekhin, AG ;
Gomonnai, AV ;
Lopushansky, VV ;
Yukhymchuk, VO ;
Schulze, S ;
Zenkevich, EI ;
Zahn, DRT .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (49) :9069-9082
[4]   Incorporation of zinc into CdS1-xSex nanocrystals in glass matrix studied by optical spectroscopies [J].
Azhniuk, YM ;
Milekhin, AG ;
Gomonnai, AV ;
Lopushansky, VV ;
Turok, II ;
Yukhymchuk, VO ;
Zahn, DRT .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 2004, 201 (07) :1578-1587
[5]   Interplay of factors affecting Raman scattering in cadmium chalcogenide nanocrystals in dielectric media [J].
Azhniuk, Yu M. ;
Hutych, Yu I. ;
Lopushansky, V. V. ;
Raevskaya, A. E. ;
Stroyuk, A. L. ;
Kuchmiy, S. Ya ;
Gomonnai, A. V. ;
Zahn, D. R. T. .
XIII INTERNATIONAL SEMINAR ON PHYSICS AND CHEMISTRY OF SOLIDS, 2007, 79
[6]   Spectroscopic studies of thermal treatment effect on the composition and size of CdS1-xSex nanocrystals in borosilicate glass [J].
Azhniuk, Yu. M. ;
Lopushansky, V. V. ;
Gomonnai, An. ;
Yukhymchuk, V. O. ;
Turok, I. I. ;
Studenyak, Ya. I. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (01) :139-146
[7]   Surface phonons in CdS1-xSex nanoparticles embedded in a dielectric medium [J].
Azhniuk, Yu. M. ;
Hutych, Yu. I. ;
Lopushansky, V. V. ;
Milekhin, A. G. ;
Gomonnai, A. V. ;
Zahn, D. R. T. .
PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, NO 9, 2009, 6 (09) :2039-+
[8]   Resonant Raman scattering studies of Cd1-xZnxS nanocrystals [J].
Azhniuk, Yu M. ;
Gomonnai, A. V. ;
Lopushansky, V. V. ;
Hutych, Yu I. ;
Turok, I. I. ;
Zahn, D. R. T. .
12TH INTERNATIONAL CONFERENCE ON PHONON SCATTERING IN CONDENSED MATTER (PHONONS 2007), 2007, 92
[9]   HRTEM, Raman and optical study of CdS1-xSex nanocrystals embedded in silicate glass [J].
Bellani, V ;
Migliori, A ;
Petrosyan, S ;
Grigorian, L ;
Petrosyan, P .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2004, 201 (13) :3023-3030
[10]   QUANTUM CONFINEMENT EFFECTS OF SEMICONDUCTING MICROCRYSTALLITES IN GLASS [J].
BORRELLI, NF ;
HALL, DW ;
HOLLAND, HJ ;
SMITH, DW .
JOURNAL OF APPLIED PHYSICS, 1987, 61 (12) :5399-5409