Electrochemically linking TEMPO to carbon via amine bridges

被引:28
作者
Geneste, F [1 ]
Moinet, C [1 ]
机构
[1] Univ Rennes 1, Inst Chim Rennes, Lab Electrochim & Organomet, CNRS UMR 6509, F-35042 Rennes, France
关键词
D O I
10.1039/b413627f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The immobilization of amino-containing compounds onto a graphite felt electrode is achieved by anodic oxidation in water. At high potentials, the specific surface of the felt increases during the grafting process, leading to high volume concentrations. The electrochemical reaction can also proceed at low potentials, giving rise to the successful covalent attachment of TEMPO onto the electrode.
引用
收藏
页码:269 / 271
页数:3
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