Effects of CTBN on the cure characteristics of DGEBA/MDA/PGE-AcAm system

被引:22
作者
Lee, JY
Choi, HK
Shim, MJ
Kim, SW
机构
[1] Univ Seoul, Dept Chem Engn, Dongdaemun Gu, Seoul 130743, South Korea
[2] NITQ, Div Chem, Kwacheon 427010, South Korea
[3] Univ Seoul, Dept Life Sci, Seoul 130743, South Korea
关键词
cure kinetics; epoxy; autocatalyst; CTBN; diffusion control;
D O I
10.1016/S0254-0584(97)02049-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effects of carboxyl-terminated butadiene acrylonitrile rubber (CTBN) on the cure characteristics of diglycidyl ether of bisphenol A (DGEBA)/4,4'-methylene dianiline (MDA)/phenyl glycidyl ether (PGE)-acetanide (AcAm) system were studied by autocatalytic cure rate expression. Cure rate at initial stage increased with the increment of the CTBN content, however, at some high stage cure rate was inverted due to the diffusion control of formed CTBN domain. The total conversion was also decreased with the increase of the CTBN content. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:272 / 276
页数:5
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