Palladium catalysed reactions of allenes, carbon monoxide and nucleophiles.

被引：47

作者：

Grigg, R ^{[1
]}

Monteith, M

Sridharan, V

Terrier, C

机构：

[1] Univ Leeds, Sch Chem, Mol Innovat Divers & Automated Synth Ctr, Leeds LS2 9JT, W Yorkshire, England

[2] Zeneca Lifesci Mol, Huddersfield HD2 1FF, W Yorkshire, England

来源：

TETRAHEDRON | 1998年 / 54卷 / 15期

关键词：

D O I：

10.1016/S0040-4020(98)00115-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydridopalladium(II) species generated in situ by oxidative addition of Pd(0) to acetic acid or acidic hydroxyl substrates (phenols, oximes) catalyse the termolecular assembly of allenes, CO and amines (primary, secondary) or oxygen nucleophiles to give methacrylamides or methacrylate esters and derivatives thereof in good to excellent yield. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3885 / 3894

页数：10

共 43 条

[41] A PALLADIUM-CATALYZED CYCLIZATION-CARBONYLATION-COUPLING REACTION BETWEEN ARYL HALIDES AND GAMMA-HYDROXYALLENES TO FORM ARYL (TETRAHYDROFURAN-2-YL)VINYL KETONES [J].