Design, Fabrication, and Modification of Nanostructured Semiconductor Materials for Environmental and Energy Applications

被引:476
作者
Hu, Xianluo
Li, Guisheng
Yu, Jimmy C. [1 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Environm Sci Programme, Shatin, Hong Kong, Peoples R China
关键词
VISIBLE-LIGHT IRRADIATION; RESOLVED MICROWAVE CONDUCTIVITY; GAS-SENSING BEHAVIOR; QUANTUM-SIZED TIO2; PHOTOCATALYTIC ACTIVITY; TITANIUM-DIOXIDE; MESOPOROUS TIO2; SOLAR-CELL; SOLVOTHERMAL SYNTHESIS; STABLE PHOTOCATALYST;
D O I
10.1021/la902142b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Considerable effort has been made to design, fabricate, and manipulate nanostructured materials by innovative approaches. The precise control of nanoscale structures will pave the way not only for elucidating unique size/shape-dependent physicochemical properties but also Cor realizing new applications in science and technology. Nanotechnology offers unprecedented opportunities for improving our daily lives and the environment in which we live. This review mainly describes our recent progress in the design, fabrication, and modification of nanostructured semiconductor materials for environmental applications. Their potential applications in the field of energy are briefly introduced. The scope of this article covers it variety of semiconductor materials. focusing particularly on TiO2-based nanostructures (e.g., pure. doped, coupled, nanoporous, mesoporous, hierarchically Porous, and ordered mesoporous TiO2). The preparation of nanoparticles, hierarchical nanoarchitectures, thin films, and single crystals by sol-gel, microemulsion, hydrothermal, sonochemical, microwave, photochemical, and nanocasting methods is discussed.
引用
收藏
页码:3031 / 3039
页数:9
相关论文
共 112 条
[51]   PHOTOCHEMISTRY AND PICOSECOND ABSORPTION-SPECTRA OF AQUEOUS SUSPENSIONS OF A POLYCRYSTALLINE TITANIUM-DIOXIDE OPTICALLY TRANSPARENT IN THE VISIBLE SPECTRUM [J].
LEPORE, GP ;
LANGFORD, CH ;
VICHOVA, J ;
VLCEK, A .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 75 (01) :67-75
[52]   Ordered mesoporous BiVO4 through nanocasting:: A superior visible light-driven photocatalyst [J].
Li, Guisheng ;
Zhang, Dieqing ;
Yu, Jimmy C. .
CHEMISTRY OF MATERIALS, 2008, 20 (12) :3983-3992
[53]   Hierarchical mesoporous grape-like titania with superior recyclability and photoactivity [J].
Li, Guisheng ;
Yu, Jimmy C. ;
Zhu, Jian ;
Cao, Yong .
MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 106 (1-3) :278-283
[54]  
Liu G, 2008, ANGEW CHEM INT EDIT, V47, P4516, DOI [10.1002/anie.200705633, 10.1002/anie.200890140]
[55]   Origin of photoactivity of nitrogen-doped titanium dioxide under visible light [J].
Livraghi, Stefano ;
Paganini, Maria Cristina ;
Giamello, Elio ;
Selloni, Annabella ;
Di Valentin, Cristiana ;
Pacchioni, Gianfranco .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) :15666-15671
[56]   Noble-metal/Cr2O3 core/shell nanoparticles as a cocatalyst for photocatalytic overall water splitting [J].
Maeda, Kazuhiko ;
Teramura, Kentaro ;
Lu, Daling ;
Saito, Nobuo ;
Inoue, Yasunobu ;
Domen, Kazunari .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (46) :7806-7809
[57]   TIME-RESOLVED MICROWAVE CONDUCTIVITY .1. TIO2 PHOTOREACTIVITY AND SIZE QUANTIZATION [J].
MARTIN, ST ;
HERRMANN, H ;
CHOI, WY ;
HOFFMANN, MR .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (21) :3315-3322
[58]   TIME-RESOLVED MICROWAVE CONDUCTIVITY .2. QUANTUM-SIZED TIO2 AND THE EFFECT OF ADSORBATES AND LIGHT-INTENSITY ON CHARGE-CARRIER DYNAMICS [J].
MARTIN, ST ;
HERRMANN, H ;
HOFFMANN, MR .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (21) :3323-3330
[59]  
MATTHEWS RW, 1994, J PHYS CHEM-US, V98, P6797
[60]   The Nature of Nitrogen-Modified Titanium Dioxide Photocatalysts Active in Visible Light [J].
Mitoraj, Dariusz ;
Kisch, Horst .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (51) :9975-9978