Novel ordered nanoporous graphitic C3N4 as a support for Pt-Ru anode catalyst in direct methanol fuel cell

被引:349
作者
Kim, Minsik [1 ]
Hwang, Sohee [1 ]
Yu, Jong-Sung [1 ]
机构
[1] Hannam Univ, Nanobio Sensor Res Team BK21, Dept Chem, Taejon 306791, South Korea
关键词
D O I
10.1039/b702213a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fabrication of graphitic carbon nitride with 3-dimensionally extended highly ordered pore arrays is described, and the N-rich porous carbon was utilized for the first time as a support for Pt-50 - Ru-50 alloy catalyst to study the support effect on the anodic performance in direct methanol fuel cells; it displays promising results as a catalyst support in the fuel cell.
引用
收藏
页码:1656 / 1659
页数:4
相关论文
共 53 条
[1]   Tunable platinum-ruthenium nanoparticle properties using microwave synthesis [J].
Bensebaa, F ;
Patrito, N ;
Le Page, Y ;
L'Ecuyer, P ;
Wang, DS .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (22) :3378-3384
[2]   Graphite nanofibers as an electrode for fuel cell applications [J].
Bessel, CA ;
Laubernds, K ;
Rodriguez, NM ;
Baker, RTK .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (06) :1115-1118
[3]   Highly efficient anode electrode materials for direct methanol fuel cell prepared with ordered and disordered arrays of carbon nanofibers [J].
Chai, GS ;
Yoon, SB ;
Yu, JS .
CARBON, 2005, 43 (14) :3028-3031
[4]   Synthesis of ordered, uniform, macroporous carbons with mesoporous walls templated by aggregates of polystyrene spheres and silica particles for use as catalyst supports in direct methanol fuel cells [J].
Chai, GS ;
Shin, IS ;
Yu, JS .
ADVANCED MATERIALS, 2004, 16 (22) :2057-+
[5]   Spherical carbon capsules with hollow macroporous core and mesoporous shell structures as a highly efficient catalyst support in the direct methanol fuel cell [J].
Chai, GS ;
Yoon, SB ;
Kim, JH ;
Yu, JS .
CHEMICAL COMMUNICATIONS, 2004, (23) :2766-2767
[6]   Ordered porous carbons with tunable pore sizes as catalyst supports in direct methanol fuel cell [J].
Chai, GS ;
Yoon, SB ;
Yu, JS ;
Choi, JH ;
Sung, YE .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (22) :7074-7079
[7]   Supported mixed metal nanoparticles as electrocatalysts in low temperature fuel cells [J].
Chan, KY ;
Ding, J ;
Ren, JW ;
Cheng, SA ;
Tsang, KY .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (04) :505-516
[8]   Carbon nanotubule membranes for electrochemical energy storage and production [J].
Che, GL ;
Lakshmi, BB ;
Fisher, ER ;
Martin, CR .
NATURE, 1998, 393 (6683) :346-349
[9]   Shock-compression of C-N precursors for possible synthesis of β-C3N4 [J].
Collins, C ;
Thadhani, N ;
Iqbal, Z .
CARBON, 2001, 39 (08) :1175-1181
[10]   Nitrogen-doping effects on electrical properties of hydrogenated microcrystalline silicon as studied by electron paramagnetic resonance and conductivity [J].
Ehara, T ;
Amino, T ;
Shinomiya, H ;
Ikoma, T ;
Akiyama, K ;
Tero-Kubota, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2000, 39 (01) :31-34