[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]:: a mononuclear 16e- ruthenium(II) catalyst for propargylic substitution and isomerization of HCCCPh2(OH)

被引：77

作者：

Cadierno, V ^{[1
]}

Díez, J ^{[1
]}

García-Garrido, SE ^{[1
]}

Gimeno, J ^{[1
]}

机构：

[1] Univ Oviedo, Dept Quim Organ & Inorgan, CSIC, IUQOEM,Unidad Asociada,Fac Quim, E-33071 Oviedo, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 23期

关键词：

D O I：

10.1039/b410812d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 16e(-) derivative [Ru(eta(3)-2-C3H4Me)(CO)(dppf)][SbF6] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl- 2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn- 1-ol into 3,3-diphenyl-2-propenal.

引用

页码：2716 / 2717

页数：2

共 22 条

[1] Transition metal complexes containing allenylidene, cumulenylidene, and related ligands
Bruce, MI
[J]. CHEMICAL REVIEWS, 1998, 98 (08) : 2797 - 2858
[2] Indenyl-ruthenium(II) allenylidene complexes containing terpenic substituents as precursors of optically active terminal alkynes: scope and limitations
Cadierno, V
Conejero, S
Gamasa, MP
Gimeno, J
[J]. DALTON TRANSACTIONS, 2003, (15) : 3060 - 3066
[3] An easy entry to dimers [{RuX(μ-X)(CO)(P∧P}2] (X = Cl, Br;: P∧P=1,1′-bis(diphenylphosphino)ferrocene, 1,1′-bis(diisopropylphosphino)ferrocene) from η3-allylruthenium(II) derivatives [RuX(η3-2-C3H4R)(CO)(P∧P)] (R = H, Me):: Efficient catalyst precursors in transfer hydrogenation of ketones
Cadierno, V
Crochet, P
Díez, J
García-Garrido, SE
Gimeno, J
[J]. ORGANOMETALLICS, 2003, 22 (25) : 5226 - 5234
[4] Cadierno V, 2001, EUR J INORG CHEM, P571
[5] Chemistry of propargyldicobalt cations: Recent developments in the Nicholas and related reactions
Green, JR
[J]. CURRENT ORGANIC CHEMISTRY, 2001, 5 (07) : 809 - 826
[6] COPPER(I)-CATALYZED AMINATION OF PROPARGYL ESTERS - SELECTIVE SYNTHESIS OF PROPARGYLAMINES, 1-ALKEN-3-YLAMINES, AND (Z)-ALLYLAMINES
IMADA, Y
YUASA, M
NAKAMURA, I
MURAHASHI, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (09) : 2282 - 2284
[7] Ruthenium-catalyzed S-propargylation of thiols enables the rapid synthesis of propargylic sulfides
Kondo, T
Kanda, Y
Baba, A
Fukuda, K
Nakamura, A
Wada, K
Morisaki, Y
Mitsudo, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (44) : 12960 - 12961
[8] Ti(OiPr)4-mediated nudeophilic substitution of propargylic esters
Mahrwald, R
Quint, S
Scholtis, S
[J]. TETRAHEDRON, 2002, 58 (49) : 9847 - 9851
[9] TiCl4-mediated amination of propargylic esters
Mahrwald, R
Quint, S
[J]. TETRAHEDRON LETTERS, 2001, 42 (09) : 1655 - 1656
[10] TiCl4-mediated nucleophilic substitution of propargylic esters
Mahrwald, R
Quint, S
[J]. TETRAHEDRON, 2000, 56 (38) : 7463 - 7468

← 1 2 3 →