Complexes of carbene analogs with Lewis bases: matrix IR spectroscopy and quantum-chemical studies

被引:23
作者
Boganov, SE [1 ]
Faustov, VI [1 ]
Egorov, MP [1 ]
Nefedov, OM [1 ]
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
关键词
carbene analogs; silylenes; germylenes; stannylenes; plumbylenes; complexes with Lewis bases; matrix IR spectroscopy; quantum-chemical calculations;
D O I
10.1023/B:RUCB.0000041298.37114.c6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The results of studies on complexes of carbene analogs ER2 (E = Si, Ge, Sn, Pb) with Lewis bases by matrix IR spectroscopy and quantum chemistry methods are considered. Trends in changes in the spectral characteristics, structures, and stability of the complexes are outlined.
引用
收藏
页码:960 / 979
页数:20
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