Development of efficient carbon anode material for a high-power and long-life lithium ion battery

被引:49
作者
Fujimoto, Hiroyuki [1 ]
机构
[1] Osaka Gas Co Ltd, Energy Technol Lab, Konohana Ku, Osaka 5540051, Japan
关键词
Carbon anode; Cyclic voltammogram; X-ray diffraction; Turbostratic structure; TURBOSTRATIC DISORDER; PHASE-DIAGRAM;
D O I
10.1016/j.jpowsour.2010.02.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Li ion battery with high power and long life is required for the hybrid electronic vehicle. A new carbon anode material called "ICOKE" has been prepared by the graphitization of coke at ca. 2000 degrees C and is shown to have excellent pulse charge/discharge characteristics and long cycle performance. The charge/discharge reaction mechanism of ICOKE was investigated in detail based on the result of cyclic voltammetry and X-ray diffraction profile change of ICOKE before and after charging. As a result, it was found that Li-intercalation reaction to ICOKE proceeds without forming higher stage compounds and the 1st and the 2nd stage compounds are directly formed. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:5019 / 5024
页数:6
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