CHARGE-DISCHARGE MECHANISM OF GRAPHITIZED MESOCARBON MICROBEADS

被引:51
作者
MABUCHI, A
FUJIMOTO, H
TOKUMITSU, K
KASUH, T
机构
[1] Research and Development Center, Osaka Gas Company, Limited, Osaka 554, 6-19-9 Torishima, Konohana-ku
关键词
D O I
10.1149/1.2048684
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The charge-discharge reaction mechanism of the graphitized mesocarbon microbead (MCMB) anode was investigated with cyclic voltammetry and x-ray diffractometry. It is concluded that the charge-discharge reaction of graphitized MCMB involves intercalation of lithium, which is essentially similar to that for graphite. However, the in-plane ordering of the stage 1 and 2 Li-GICs obtained from the graphitized MCMB is not LiC6 like graphite, but is close to LiC8, according to the results of both x-raji diffractometry and cyclic voltammetry.
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页码:3049 / 3051
页数:3
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