Self- and hetero-recognition in the guest-controlled assembly of Pd(II)-linked cages from two different ligands

被引：98

作者：

Hiraoka, S ^{[1
]}

Kubota, Y ^{[1
]}

Fujita, M ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, CREST,Japan Sci & Technol Cooperat, Nagoya, Aichi 4648603, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 16期

关键词：

D O I：

10.1039/b004271o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The equilibration of cage-like receptors, M-3(L-1)(2) + M-3(L-2)(2) reversible arrow 2 M-3(L-1)(L-2), was efficiently controlled by appropriate guest addition: large (spherical) or small (flat) guests stabilized the homoleptic cages (M-3(L-1)(2) or M-3(L-2)(2)) while medium-sized guests preferred the heteroleptic cage (M-3(L-1)(L-2)).

引用

页码：1509 / 1510

页数：2

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