Selective synthesis and characterization of famatinite nanofibers and tetrahedrite nanoflakes

被引:60
作者
An, CH
Jin, Y
Tang, K [1 ]
Qian, Y
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Peoples R China
关键词
D O I
10.1039/b210703a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High quality semiconducting famatinite (Cu3SbS4) nanofibers and tetradrite (Cu12Sb4S13) nanoflakes have been selectively synthesized through mild hydrothermal and solvothermal synthesis routes, respectively. The morphology and phase of the products can be successfully controlled by choosing appropriate reaction media to adjust the dynamics of the reaction process. It was found that reaction temperature is an important factor influencing the phase purity of the products. This method may provide a general route for the selective preparation of other semiconducting multinary sulfide nanocrystallites.
引用
收藏
页码:301 / 303
页数:3
相关论文
共 27 条
[1]  
[Anonymous], TERNARY DIAMOND SEMI
[2]   SYNTHESIS AND STRUCTURE OF TA4SITE4, A NEW LOW-DIMENSIONAL MATERIAL [J].
BADDING, ME ;
DISALVO, FJ .
INORGANIC CHEMISTRY, 1990, 29 (20) :3952-3954
[3]   Physical and chemical changes of sulphides during intensive grinding in organic liquids [J].
Balaz, P ;
Mockovciakova, A ;
Boldizarova, E ;
Ficeriova, J .
POWDER TECHNOLOGY, 1998, 98 (01) :74-78
[4]   Synthesis and characterization of the first liquid single-source precursors for the deposition of ternary chalcopyrite (CuInS2) thin film materials [J].
Banger, KK ;
Cowen, J ;
Hepp, AF .
CHEMISTRY OF MATERIALS, 2001, 13 (11) :3827-+
[5]   BONDING RELATIONSHIPS IN SOME TERNARY AND QUATERNARY PHOSPHIDE AND TETRAHEDRITE STRUCTURES - [AG6M4P12]M6', CU12+XSB4S13 AND CU14-XSB4S13, LN6NI6P17 [J].
BULLETT, DW ;
DAWSON, WG .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1986, 19 (29) :5837-5847
[6]   Synthesis, electrical conductivity, and crystal structure of Cu4Sn7S16 and structure refinement of Cu2SnS3 [J].
Chen, XA ;
Wada, H ;
Sato, A ;
Mieno, M .
JOURNAL OF SOLID STATE CHEMISTRY, 1998, 139 (01) :144-151
[7]   SOLID-STATE CHEMISTRY - A REDISCOVERED CHEMICAL FRONTIER [J].
DISALVO, FJ .
SCIENCE, 1990, 247 (4943) :649-655
[8]  
HISAYUKI N, 1969, JPN J APPL PHYS, V8, P443
[9]   Solvothermal reaction route to nanocrystalline semiconductors AgMS2 (M = Ga, In) [J].
Hu, JQ ;
Lu, QY ;
Tang, KB ;
Qian, YT ;
Zhou, G ;
Liu, XM .
CHEMICAL COMMUNICATIONS, 1999, (12) :1093-1094
[10]   A NOTE ON THE BONDING, OPTICAL-SPECTRUM AND COMPOSITION OF TETRAHEDRITE [J].
JEANLOZ, R ;
JOHNSON, ML .
PHYSICS AND CHEMISTRY OF MINERALS, 1984, 11 (01) :52-54