Characterization of the chromophores of pyoverdins and related siderophores by electrospray tandem mass spectrometry

被引:38
作者
Budzikiewicz, Herbert
Schaefer, Mathias
Fernandez, Diana Uria
Matthijs, Sandra
Cornelis, Pierre
机构
[1] Univ Cologne, Inst Organ Chem, D-50939 Cologne, Germany
[2] Waters MS Technol Ctr, Manchester, Lancs, England
[3] Vrije Univ Brussels, Lab Microbial Interact, B-1050 Brussels, Belgium
关键词
Pseudomonas siderophores; mass spectrometrical characterization; new ferribactin;
D O I
10.1007/s10534-006-9021-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Characteristic fragment ions of the various chromophores of the pyoverdin siderophore family obtained by collision activated dissociation of the [M+2H](2+) ions are reported allowing unambiguous identification. Tandem mass spectrometrical studies revealed the existence of the first example of a ferribactin with a succinamide side chain, and they add some information to the problem in which way a malic acid side chain is attached to the chromophore.
引用
收藏
页码:135 / 144
页数:10
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