Formation of surface nano-step structures and improvement of photocatalytic activities of NaTaO3 by doping of alkaline earth metal ions

被引:74
作者
Iwase, A [1 ]
Kato, H [1 ]
Okutomi, H [1 ]
Kudo, A [1 ]
机构
[1] Tokyo Univ Sci, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
关键词
D O I
10.1246/cl.2004.1260
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Powders of NaTaO3 doped with alkaline earth metal ions were prepared. Scanning electron microscopy observation revealed that NaTaO3 crystals doped with Ca, Sr, and Ba became smaller than nondoped NaTaO3 crystals. In addition, nano-step structures were constructed on the surfaces of NaTaO3 doped with Ca, Sr, and Ba. The photocatalytic activity of water splitting on NaTaO3 was improved by the doping of Ca, Sr, and Ba. It is due to the small particle size and the formation of surface nano-step structures as observed for La doping.
引用
收藏
页码:1260 / 1261
页数:2
相关论文
共 10 条
[1]   Photo- and mechano-catalytic overall water splitting reactions to form hydrogen and oxygen on heterogeneous catalysts [J].
Domen, K ;
Kondo, JN ;
Hara, M ;
Takata, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (06) :1307-1331
[2]   Effects of acceptor doping to KTaO3 on photocatalytic decomposition of pure H2O [J].
Ishihara, T ;
Nishiguchi, H ;
Fukamachi, K ;
Takita, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (01) :1-3
[3]   Highly efficient water splitting into H2 and O2 over lanthanum-doped NaTaO3 photocatalysts with high crystallinity and surface nanostructure [J].
Kato, H ;
Asakura, K ;
Kudo, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :3082-3089
[4]   Photocatalytic water splitting into H2 and O2 over various tantalate photocatalysts [J].
Kato, H ;
Kudo, A .
CATALYSIS TODAY, 2003, 78 (1-4) :561-569
[5]   Photocatalyst materials for water splitting [J].
Kudo, A .
CATALYSIS SURVEYS FROM ASIA, 2003, 7 (01) :31-38
[6]   Photocatalytic properties of layered perovskite tantalates, MLnTa2O7 (M = Cs, Rb, Na, and H; Ln = La, Pr, Nd, and Sm) [J].
Machida, M ;
Miyazaki, K ;
Matsushima, S ;
Arai, M .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (06) :1433-1437
[7]   Effect of Zr substitution for Ti in KLaTiO4 for photocatalytic water splitting [J].
Reddy, VR ;
Hwang, DW ;
Lee, JS .
CATALYSIS LETTERS, 2003, 90 (1-2) :39-43
[8]   Photocatalytic activity for water decomposition of indates with octahedrally coordinated d10 configuration.: I.: Influences of preparation conditions on activity [J].
Sato, J ;
Saito, N ;
Nishiyama, H ;
Inoue, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (31) :7965-7969
[9]   REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].
SHANNON, RD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767
[10]   Photocatalytic water splitting on hydrated layered perovskite tantalate A2SrTa2O7•nH2O ( A = H, K, and Rb) [J].
Shimizu, K ;
Tsuji, Y ;
Hatamachi, T ;
Toda, K ;
Kodama, T ;
Sato, M ;
Kitayama, Y .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (05) :1064-1069