In search of ruthenium(II) complexes based on tridentate polypyridine ligands that feature long-lived room-temperature luminescence: The multichromophore approach

被引:115
作者
Passalacqua, R
Loiseau, F
Campagna, S
Fang, YQ
Hanan, GS [1 ]
机构
[1] Univ Messina, Dipartimento Chim Inorgan Chim Anal & Chim Fis, I-98166 Messina, Italy
[2] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
关键词
chromophores; luminescence; N ligands; photochemistry; ruthenium;
D O I
10.1002/anie.200250613
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Time trials: A ruthenium (II) complex based on tridentate polypyridine ligands (see picture) featuring the longest luminescence lifetime (1.8 μs) ever reported is described. This new species has been obtained by applying the multichromophore approach, in which the various metal- and organic-based chromophores are only weakly interacting, so that their individual properties are essentially maintained.
引用
收藏
页码:1608 / 1611
页数:4
相关论文
共 39 条
[1]  
[Anonymous], 1999, J CHEM EDUC
[2]   Palladium-catalysed cross-coupling reactions of ruthenium bis-terpyridyl complexes: strategies for the incorporation and exploitation of boronic acid functionality [J].
Aspley, CJ ;
Williams, JAG .
NEW JOURNAL OF CHEMISTRY, 2001, 25 (09) :1136-1147
[3]   Artificial molecular-level machines: Which energy to make them work? [J].
Ballardini, R ;
Balzani, V ;
Credi, A ;
Gandolfi, MT ;
Venturi, M .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :445-455
[4]   Luminescent and redox-active polynuclear transition metal complexes [J].
Balzani, V ;
Juris, A ;
Venturi, M ;
Campagna, S ;
Serroni, S .
CHEMICAL REVIEWS, 1996, 96 (02) :759-833
[5]   Photoactive molecular wires based on metal complexes [J].
Barigelletti, F ;
Flamigni, L .
CHEMICAL SOCIETY REVIEWS, 2000, 29 (01) :1-12
[6]   3,3',5,5'-TETRAPYRIDYLBIPHENYL - A BISCYCLOMETALATING BRIDGING LIGAND WITH A HIGH COUPLING ABILITY IN RU(III),RU(II) MIXED-VALENCE SYSTEMS [J].
BELEY, M ;
COLLIN, JP ;
LOUIS, R ;
METZ, B ;
SAUVAGE, JP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) :8521-8522
[7]   Photoinduced ultrafast dye-to-semiconductor electron injection from nonthermalized and thermalized donor states [J].
Benkö, G ;
Kallioinen, J ;
Korppi-Tommola, JEI ;
Yartsev, AP ;
Sundström, V .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (03) :489-493
[8]  
Benniston AC, 1997, NEW J CHEM, V21, P405
[9]   NOVEL SYNTHESIS OF A DOUBLY CYCLOMETALATED DIRUTHENIUM COMPLEX WITH STRONGLY COUPLED METAL CENTERS [J].
CONSTABLE, EC ;
THOMPSON, AMWC ;
GREULICH, S .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (18) :1444-1446
[10]   Stille cross-coupling of metal complexes [J].
Dunne, SJ ;
Constable, EC .
INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (05) :167-169