Expanding the family of phospholane-based ligands: 1,2-bis(2,5-diphenylphospholano)ethane

被引：55

作者：

Pilkington, CJ ^{[1
]}

Zanotti-Gerosa, A ^{[1
]}

机构：

[1] Chirotech Technol Ltd, Dowpharma, Unit 321, Cambridge CB4 0WG, England

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 08期

关键词：

D O I：

10.1021/ol0341952

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,2-Bis(2,5-diphenylphospholano)ethane (Ph-BPE) has been synthesized for the first time through employment of an undemanding synthetic pathway, The new ligand exhibits enhanced activity and selectivity over the existing members of the BPE ligand family in rhodium-catalyzed asymmetric hydrogenation.

引用

页码：1273 / 1275

页数：3

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