Reactivity of [Ru3(CO)12]with dibenzothiophene, methylbenzothiophene, and methyldibenzothiophene

被引：30

作者：

Chehata, A ^{[1
]}

Oviedo, A ^{[1
]}

Arévalo, A ^{[1
]}

Bernès, S ^{[1
]}

García, JJ ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 08期

关键词：

D O I：

10.1021/om030069q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dibenzothiophene (DBT) with [Ru-3(12)2(12)8(5)2((CO))] in heptane affords the dinuclear complex [Ru((C)H()(m-CO)(CO))], derived from a double C-S bond activation-desulfurization process. The reaction of this complex with H under very mild conditions leads to the release of biphenyl.

引用

页码：1585 / 1587

页数：3

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