Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes:: a new tin-free homolytic route to β- and γ-lactams

被引：45

作者：

Jackson, LV ^{[1
]}

Walton, JC ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 23期

关键词：

D O I：

10.1039/b007454n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alternative dissociation to methyl radicals: beta- and gamma -lactams were obtained from ring closures of suitably unsaturated model compounds.

引用

页码：2327 / 2328

页数：2

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