Ferrocenyl monophosphine ligands: Synthesis and applications in the Suzuki-Miyaura coupling of aryl chlorides

被引：85

作者：

Baillie, C ^{[1
]}

Zhang, LX ^{[1
]}

Xiao, JL ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 22期

关键词：

D O I：

10.1021/jo048963u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ferrocenyl monophosphine ligands have been developed by a method based on palladium-catalyzed Suzuki-Miyaura coupling. The modular procedure creates a rapid synthesis of phosphines with diverse properties. The electron-rich phosphines have been successfully applied to the Suzuki-Miyaura coupling of activated and deactivated aryl chlorides, with low catalyst loading being feasible in the synthesis of tris-ortho-substituted biaryls.

引用

页码：7779 / 7782

页数：4

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