Hexa-μ-chloro-μ4-oxo-tetrakis-{[5-(2,4,6-trimethylphenyl)pyrazole-κN2]copper(II)}

被引:8
作者
Liu, XM [1 ]
Kilner, CA [1 ]
Halcrow, MA [1 ]
机构
[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷
关键词
D O I
10.1107/S0108270103002853
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, [Cu4Cl6O(C12H14N2)(4)], is a new example of the well known [Cu-4(mu(4)-O)(mu-X)(6)L-4] class of complex (X- is Cl-, Br- or I-, and L is a monodentate ligand). The molecule has crystallographic C-2 symmetry, with two Cl- ions on each edge of a Cu-4 tetrahedron. Two of these, on opposite edges of the tetrahedron, accept intramolecular hydrogen bonds from two of the pyrazole N-H donors.
引用
收藏
页码:M100 / M102
页数:3
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