Influence of precursor on the thermally induced synthesis dysprosium manganite with perovskite structure

被引:12
作者
Carp, O
Patron, L
Ianculescu, A
Crisan, D
Dragan, N
Olar, R
机构
[1] IG Murgulescu Inst Phys Chem, Bucharest 77208, Romania
[2] Univ Toulouse 3, Lab Chim Mat Inorgan & Energet, F-31062 Toulouse, France
[3] Univ Bucharest, Dept Inorgan Chem, Bucharest 71267, Romania
关键词
manganese perovskite; Mn-Dy coordination compounds; thermal behaviour;
D O I
10.1023/A:1023992308398
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermal behaviour of two coordination compounds [MnDy(malic)(3)].5H(2)O and [MnDy(gluconic)(3)].12H(2)O has been studied to evaluate their suitability for dysprosium manganese perovskite synthesis. A decomposition scheme is proposed leading to perovskites with orthorhombic (malic precursor) and hexagonal (gluconic precursor) structures which were obtained after a heating treatment of 4 h at 1000degreesC with one-hour plateau at 500degreesC.
引用
收藏
页码:253 / 261
页数:9
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