Directly assembled CdSe quantum dots on TiO2 in aqueous solution by adjusting pH value for quantum dot sensitized solar cells

被引:99
作者
Chen, J. [2 ]
Zhao, D. W. [1 ]
Song, J. L. [3 ]
Sun, X. W. [1 ]
Deng, W. Q. [3 ]
Liu, X. W. [3 ]
Lei, W. [2 ]
机构
[1] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639798, Singapore
[2] Southeast Univ, Sch Elect Sci & Engn, Nanjing 210096, Peoples R China
[3] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637616, Singapore
基金
美国国家科学基金会;
关键词
Quantum dot; Solar cell; CdSe; pH value; EFFICIENCY; MULTIPLICATION;
D O I
10.1016/j.elecom.2009.10.003
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We report an improved quantum dot sensitized solar cell (QDSSC) by loading mercaptopropionic acid (MPA)-capped CdSe QDs on TiO2 film in aqueous solution. Under suitable pH value, a power conversion efficiency of 1.19% and an incident photon to current conversion efficiency of 26% for the QDSSC were obtained at AM1.5G irradiation. The improved performance of QDSSC is attributed to the large loading and good coverage of QDs on TiO2 film with optimal pH value. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2265 / 2267
页数:3
相关论文
共 22 条
[11]  
Lee HJ, 2007, B KOREAN CHEM SOC, V28, P953
[12]   Chemical bath deposition of CdS quantum dots on vertically aligned ZnO nanorods for quantum dots-sensitized solar cells [J].
Lee, Wonjoo ;
Min, Sun Ki ;
Dhas, Vivek ;
Ogale, Satishchandra B. ;
Han, Sung-Hwan .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (01) :103-106
[13]   Highly Efficient Quantum-Dot-Sensitized Solar Cell Based on Co-Sensitization of CdS/CdSe [J].
Lee, Yuh-Lang ;
Lo, Yi-Siou .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (04) :604-609
[14]   Quantum-dot-sensitized solar cells: Assembly of CdS-quantum-dots coupling techniques of self-assembled monolayer and chemical bath deposition [J].
Lin, Sheng-Chih ;
Lee, Yuh-Lang ;
Chang, Chi-Hsiu ;
Shen, Yu-Jen ;
Yang, Yu-Min .
APPLIED PHYSICS LETTERS, 2007, 90 (14)
[15]   Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells [J].
Nazeeruddin, MK ;
Péchy, P ;
Renouard, T ;
Zakeeruddin, SM ;
Humphry-Baker, R ;
Comte, P ;
Liska, P ;
Cevey, L ;
Costa, E ;
Shklover, V ;
Spiccia, L ;
Deacon, GB ;
Bignozzi, CA ;
Grätzel, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) :1613-1624
[16]   Exciton multiplication and relaxation dynamics in quantum dots: Applications to ultrahigh-efficiency solar photon conversion [J].
Nozik, AJ .
INORGANIC CHEMISTRY, 2005, 44 (20) :6893-6899
[17]   HARD AND SOFT ACIDS AND BASES [J].
PEARSON, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (22) :3533-&
[18]   High-efficiency carrier multiplication through direct photogeneration of multi-excitons via virtual single-exciton states [J].
Schaller, RD ;
Agranovich, VM ;
Klimov, VI .
NATURE PHYSICS, 2005, 1 (03) :189-194
[19]   Effect of ZnS coating on the photovoltaic properties of CdSe quantum dot-sensitized solar cells [J].
Shen, Qing ;
Kobayashi, Junya ;
Diguna, Lina J. ;
Toyoda, Taro .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (08)
[20]   DETAILED BALANCE LIMIT OF EFFICIENCY OF P-N JUNCTION SOLAR CELLS [J].
SHOCKLEY, W ;
QUEISSER, HJ .
JOURNAL OF APPLIED PHYSICS, 1961, 32 (03) :510-&