A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

被引：38

作者：

Bebbington, Magnus W. P. ^{[1
,2
]}

Bontemps, Sebastien ^{[1
,2
]}

Bouhadir, Ghenwa ^{[1
,2
]}

Hanton, Martin J. ^{[3
]}

Tooze, Robert P. ^{[3
]}

van Rensburg, Hendrick ^{[3
]}

Bourissou, Didier ^{[1
,2
]}

机构：

[1] Univ Toulouse, UPS, LHFA, F-31062 Toulouse, France

[2] CNRS, UMR 5069, LHFA, F-31062 Toulouse, France

[3] Sasol Technol UK, St Andrews KY16 9ST, Fife, Scotland

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 08期

关键词：

TRANSITION-METAL-COMPLEXES; MIYAURA COUPLING PROCESSES; FREE HYDROGEN ACTIVATION; RHODIUM(I) COMPLEXES; PALLADIUM COMPLEXES; FERROCENYL LIGANDS; AMBIPHILIC LIGANDS; ACTIVE CATALYST; BORON; DONOR;

D O I：

10.1039/c0nj00117a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new ambiphilic ligand Ph2P-(1,1'-ferrocenyl)-BMes(2), prepared by sequential lithiation/electrophilic trapping of 1,1'-dibromoferrocene, adopts a monomeric structure free of dative P -> B and Fe -> B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

引用

页码：1556 / 1559

页数：4

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