A facile strategy for the fabrication of highly stable superhydrophobic cotton fabric using amphiphilic fluorinated triblock azide copolymers

被引：79

作者：

Li, Guang ^{[1
]}

Zheng, Haiting ^{[1
]}

Wang, Yanxue ^{[1
]}

Wang, Hu ^{[1
]}

Dong, Qibao ^{[1
]}

Bai, Ruke ^{[1
]}

机构：

[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Dept Polymer Sci & Engn, Hefei 230026, Peoples R China

来源：

POLYMER | 2010年 / 51卷 / 09期

关键词：

Azide polymers; Reversible addition fragmentation chain transfer (RAFT) polymerization; Superhydrophobic surface; GAMMA-RAY IRRADIATION; WALLED CARBON NANOTUBES; TEMPERATURE RAFT POLYMERIZATION; FREE-RADICAL COPOLYMERIZATION; ROOM-TEMPERATURE; CLICK FUNCTIONALIZATION; SURFACE MODIFICATION; REDOX INITIATION; METHYL ACRYLATE; CROSS-LINKING;

D O I：

10.1016/j.polymer.2010.03.002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Amphiphilic triblock azide copolymers containing poly(ethylene glycol) (PEG) and poly(22,3,4,4,4-hexafluorobutyl acrylate) blocks have been synthesized through room temperature RAFT polymerization using redox initiation and were successfully used to fabricate superhydrophobic cotton fabric by a facile approach. The copolymers were covalently attached to the surface of the cotton fabric by the reaction of azide groups with the cotton fibres based on nitrene chemistry via UV irradiation. Due to introducing the fluorinated polymer chains, the cotton fabric was transformed from hydrophilicity to super-hydrophobicity with a water contact angle of 155 degrees. Since the fluorinated polymer chains were covalently attached on the surface of the cotton fabric, the superhydrophobic cotton fabric possessed high stability and chemical durability. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1940 / 1946

页数：7

共 54 条

[1] Influence of progressive cross-linking on dewetting of polystyrene thin films [J].

Al Akhrass, Samer ;

Ostaci, Roxana-Viorela ;

Grohens, Yves ;

Drockenmuller, Eric ;

Reiter, Guenter .

LANGMUIR, 2008, 24 (05) :1884-1890

[2] Silicone nanofilaments and their application as superhydrophobic coating [J].

Artus, Georg R. J. ;

Jung, Stefan ;

Zimmermann, Jan ;

Gautschi, Hans-Peter ;

Marquardt, Klaus ;

Seeger, Stefan .

ADVANCED MATERIALS, 2006, 18 (20) :2758-+

[3] Synthesis and characterization of glycidyl azide polymers using isotactic and chiral poly(epichlorohydrin)s [J].

Brochu, S ;

Ampleman, G .

MACROMOLECULES, 1996, 29 (17) :5539-5545

[4]

Chang TC, 1996, J POLYM SCI POL CHEM, V34, P3337, DOI 10.1002/(SICI)1099-0518(19961130)34:16<3337::AID-POLA10>3.0.CO

[5]

2-H

[6] Scalable Functional Group Engineering of Carbon Nanotubes by Improved One-Step Nitrene Chemistry [J].

Gao, Chao ;

He, Hongkun ;

Zhou, Li ;

Zheng, Xing ;

Zhang, Yu .

CHEMISTRY OF MATERIALS, 2009, 21 (02) :360-370

[7] Artificial lotus leaf prepared using a 1945 patent and a commercial textile [J].

Gao, Lichao ;

McCarthy, Thomas J. .

LANGMUIR, 2006, 22 (14) :5998-6000

[8]

GAO Q, 2009, IND ENG CHEM RES, V48, P9797

[9] Thermal behaviour of poly(allyl azide) [J].

Gaur, B ;

Lochab, B ;

Choudhary, V ;

Varma, IK .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 71 (02) :467-479

[10] A STUDY ON THE THERMAL-DECOMPOSITION OF MIXTURES CONTAINING AN ENERGETIC BINDER AND A NITRAMINE [J].

GER, MD ;

HWU, WH ;

HUANG, CC .

THERMOCHIMICA ACTA, 1993, 224 :127-140

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