Highly selective anodic monofluorination of 4-arylthio-1,3-dioxolan-2-ones: a marked solvent effect on product selectivity

被引：36

作者：

Ishii, H ^{[1
]}

Yamada, N ^{[1
]}

Fuchigami, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b004652n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This is the first example of a solvent effect on fluorinated product selectivity; anodic fluorination of 4-arylthio-1,3-dioxolan-2-ones in CH2Cl2 containing a fluoride supporting electrolyte using an undivided cell provided the fluorodesulfurization product, 4-fluoro-1,3-dioxolan-2-one preferentially while anodic fluorination in DME resulted in alpha-fluorination, without desulfurization, selectively.

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页码：1617 / 1618

页数：2

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