Polyelectrolyte multilayers containing photoreactive groups

被引:28
作者
Laschewsky, A [1 ]
Wischerhoff, E [1 ]
Bertrand, P [1 ]
Delcorte, A [1 ]
机构
[1] UNIV CATHOLIQUE LOUVAIN,DEPT MAT & PROC SCI,B-1348 LOUVAIN,BELGIUM
关键词
D O I
10.1002/macp.1997.021981021
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of a photocrosslinkable polycation and its use in the assembly of alternating polyelectrolyte multilayers are described. Characterization by UV/VIS spectroscopy and time-of-flight secondary ion mass spectroscopy (ToF-SIMS) reveals the influence of the crosslinking on the physical properties of the build-ups. Remarkably, the assembly of such multilayer structures is not only possible on hydrophilic substrates, but also on apolar poly(propylene). In this case, the crosslinkable polycation turns out to be especially useful to obtain stable, solvent resistant coatings.
引用
收藏
页码:3239 / 3253
页数:15
相关论文
共 22 条
[11]   A new route to thin polymeric, non-centrosymmetric coatings [J].
Laschewsky, A ;
Mayer, B ;
Wischerhoff, E ;
Arys, X ;
Bertrand, P ;
Delcorte, A ;
Jonas, A .
THIN SOLID FILMS, 1996, 284 :334-337
[12]   Polyelectrolyte complexes at interfaces [J].
Laschewsky, A ;
Mayer, B ;
Wischerhoff, E ;
Arys, X ;
Jonas, A .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1996, 100 (06) :1033-1038
[13]   Molecular recognition by hydrogen bonding in polyelectrolyte multilayers [J].
Laschewsky, A ;
Wischerhoff, E ;
Denzinger, S ;
Ringsdorf, H ;
Delcorte, A ;
Bertrand, P .
CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (01) :34-38
[14]  
LASCHEWSKY A, UNPUB MACROMOLECULES
[15]  
Neises B., 1978, ANGEW CHEM, V90, P556, DOI [DOI 10.1002/ANGE.19780900718, 10.1002/ange.19780900718]
[16]   POLYMERIZATION OF 10,12-DOCOSADIYNE-1,22-DISULFATE IN SELF-ASSEMBLED MULTILAYERS [J].
SAREMI, F ;
TIEKE, B .
ADVANCED MATERIALS, 1995, 7 (04) :378-380
[17]   MICROSCOPE IMAGING BY TIME-OF-FLIGHT SECONDARY ION MASS-SPECTROMETRY [J].
SCHUELER, BW .
MICROSCOPY MICROANALYSIS MICROSTRUCTURES, 1992, 3 (2-3) :119-139
[18]   Assembly of polyelectrolyte multilayer films by consecutively alternating adsorption of polynucleotides and polycations [J].
Sukhorukov, GB ;
Mohwald, H ;
Decher, G ;
Lvov, YM .
THIN SOLID FILMS, 1996, 284 :220-223
[19]   ELECTROLUMINESCENT PROPERTIES OF SELF-ASSEMBLED POLYMER THIN-FILMS [J].
TIAN, J ;
WU, CC ;
THOMPSON, ME ;
STURM, JC ;
REGISTER, RA ;
MARSELLA, MJ ;
SWAGER, TM .
ADVANCED MATERIALS, 1995, 7 (04) :395-398
[20]   DYNAMIC LIGHT-SCATTERING EXPERIMENTS WITH AQUEOUS-SOLUTIONS OF POLYELECTROLYTES OF LOW CHARGE-DENSITY ALONG THE POLYMER-CHAIN IN THE PRESENCE OF SALT [J].
TOPP, A ;
BELKOURA, L ;
WOERMANN, D .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1995, 99 (05) :730-735