Polymer-clay nanocomposites based on blends of polyamide-6 and polyethylene

被引:66
作者
Mehrabzadeh, M
Kamal, MR
机构
[1] McGill Univ, Dept Chem Engn, Montreal, PQ H3A 2B2, Canada
[2] Iran Polymer Inst, Tehran, Iran
关键词
nanocomposites; polyamide-6; high density polyethylene; crystallization; morphology;
D O I
10.1002/cjce.5450800610
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The preparation of polyamide-6/clay, high-density polyethylene/clay, and high-density polyethylen/polyamide-6/clay nanocomposites is considered. X-ray diffraction (XRD), differential scanning calorimetry (DSC), and Fourier Transform Infrared (FTIR) measurements show that the clay enhances the crystallization of the gamma-form of polyamide-6. The clay also acts as a nucleation agent and causes a reduction of spherulitte size. Scanning electron microscopy (SEM) analysis of fracture surfaces shows that the clay reduces the PA-6 particle size in the HDPE/PA-6/clay nanocomposites and changes the morphology. Mechanical properties and the effect of maleated polyethylene are also reported.
引用
收藏
页码:1083 / 1092
页数:10
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