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Dimeric bridged and chelated alkali metal (Li and Na) bis(iminophosphorano)methanide complexes with contrasting structures

被引：54
作者：
Babu, RPK
Aparna, K
McDonald, R
Cavell, RG [1 ]
机构：
[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada
[2] Univ Alberta, Xray Struct Determinat Lab, Edmonton, AB T6G 2G2, Canada
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 21期
关键词：
D O I：
10.1021/ic991364z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Lithium (2) and sodium (3) complexes of deprotonated bis(iminophosphorano)methane, CH2(Ph2P=NSiMe3)(2), 1, differ in that the former is a C-bridged and the latter is an N-bridged dimer in the solid state. [GRAPHICS]
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页码：4981 / +
页数：5
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