Mono (alkylcyclopentadienyl) complexes of barium and strontium

被引：27

作者：

Sitzmann, H ^{[1
]}

Weber, F ^{[1
]}

Walter, MD ^{[1
]}

Wolmershäuser, G ^{[1
]}

机构：

[1] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 09期

关键词：

D O I：

10.1021/om020034a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mono(ring) complexes [{(C5H2R3-1,2,4)BaI(THF)(2)}(infinity)] (1-Ba; R = CMe3) and [{(C5HR4)BaI(THF)(2)}(2)] (2-Ba; R = CHMe2) have been synthesized from BaI2 and the corresponding sodium cyclopentadienides. 2-Sr has been obtained both from SrI2 and NaC5HR4 (R = CHMe2) or by ligand redistribution between octaisopropylstrontocene (3-Sr) and SrI2. The chlorobridged calcium complex [{(C5H2R3-1,2,4)CaCl(DME)}(2)] (4-Ca, R = CMe3) is available from CaCl2 and NaC5H2R3-1,2,4. The crystal structures of 1-Ba, 2-Ba, and 4-Ca have been determined.

引用

页码：1931 / 1936

页数：6

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