Comparison of the NMR enantiodifferentiation of a chiral ruthenium(II) complex of C2 symmetry using the TRISPHAT anion and a lanthanide shift reagent

被引：20

作者：

Bruylants, G

Bresson, C

Boisdenghien, A

Pierard, F

Kirsch-De Mesmaeker, A

Lacour, J

Bartik, K

机构：

[1] Free Univ Brussels, Ecole Polytech, B-1000 Brussels, Belgium

[2] Free Univ Brussels, Serv Chim Organ & Photochim, Fac Sci, B-1000 Brussels, Belgium

[3] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 04期

关键词：

D O I：

10.1039/b211419d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tris[tetrachlorobenzenediolato]phosphate(V) anion (TRISPHAT) is known to be an efficient NMR chiral shift agent for various chiral cationic species. Here we compare the efficiency of TRISPHAT and of a chiral lanthanide shift reagent for the determination of the enantiomeric purity of the chiral building block [Ru(phen)(2)py(2)](2+) which possesses C-2 symmetry. We also discuss our results in terms of the geometry of interaction between the Ru(II) complex and the TRISPHAT anion.

引用

页码：748 / 751

页数：4

共 41 条

[1] APPLICATION OF CHIRAL LANTHANIDE-INDUCED SHIFT-REAGENTS TO OPTICALLY-ACTIVE CATIONS - THE USE OF TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-(+)-CAMPHORATO]EUROPIUM(III) TO DETERMINE THE ENANTIOMERIC PURITY OF TRIS(PHENANTHROLINE)RUTHENIUM(II) DICHLORIDE
BARTON, JK
NOWICK, JS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (24) : 1650 - 1652
[2] BIS-1,10-PHENANTHROLINE COMPLEXES OF DIVALENT RUTHENIUM
BOSNICH, B
DWYER, FP
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1966, 19 (12) : 2229 - &
[3] Applications of luminescent transition platinum group metal complexes to sensor technology and molecular probes
Demas, JN
DeGraff, BA
[J]. COORDINATION CHEMISTRY REVIEWS, 2001, 211 : 317 - 351
[4] Solid-state organic light-emitting diodes based on tris(2,2′-bipyridine)ruthenium(II) complexes
Gao, FG
Bard, AJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (30) : 7426 - 7427
[5] LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS
HAGFELDT, A
GRATZEL, M
[J]. CHEMICAL REVIEWS, 1995, 95 (01) : 49 - 68
[6] Conversion of a new chiral reagent Δ-[Ru(bpy)2(dmso)Cl] PF6 to Δ-[Ru(bpy)2(dmbpy)]PF6Cl with 96.8% retention of chirality (dmbpy = 4,4′-dimethyl-2,2′-bipyridine)
Hesek, D
Inoue, Y
Everitt, SRL
Ishida, H
Kunieda, M
Drew, MGB
[J]. CHEMICAL COMMUNICATIONS, 1999, (05) : 403 - 404
[7] ENANTIOMERICALLY PURE CHIRAL RU-II(L-BOOLEAN-AND-L)(2) BUILDING-BLOCKS FOR COORDINATION-COMPOUNDS
HUA, X
VONZELEWSKY, A
[J]. INORGANIC CHEMISTRY, 1995, 34 (23) : 5791 - 5797
[8] 1ST STEREOSPECIFIC PREPARATION OF A POLYNUCLEAR COORDINATION COMPOUND - USE OF LAMBDA-RU(II)(ORTHO-PHEN)2 AS A CHIRAL BUILDING BLOCK
HUA, X
VONZELEWSKY, A
[J]. INORGANIC CHEMISTRY, 1991, 30 (20) : 3796 - 3798
[9] Jodry JJ, 2000, CHEM-EUR J, V6, P4297, DOI 10.1002/1521-3765(20001201)6:23<4297::AID-CHEM4297>3.0.CO
[10] 2-#

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