Peroxovanadium-catalyzed oxidative esterification of aldehydes

被引：114

作者：

Gopinath, R ^{[1
]}

Barkakaty, B ^{[1
]}

Talukdar, B ^{[1
]}

Patel, BK ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 07期

关键词：

D O I：

10.1021/jo0266902

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The peroxovanadium species generated from V2O5 and hydrogen peroxide, which is liberated from peroxy salts such as sodium perborate (SPB) or sodium percarbonate (SPC), transform aldehydes directly into esters in an alcoholic medium. Monoesters of diols have been achieved directly in one pot from aldehydes. High catalytic turnover number combined with inexpensive, easily available reagents and innocuous side products from the reaction make it a suitable alternative for the synthesis of esters from aldehydes.

引用

页码：2944 / 2947

页数：4

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