Mode-coupling theory for translational and orientational dynamics near the ideal glass transition

被引:18
作者
Schilling, R [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, D-55099 Mainz, Germany
关键词
D O I
10.1088/0953-8984/12/29/303
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We briefly review the molecular mode-coupling theory which takes into account both the translational and the orientational degrees of freedom. Depending on the symmetry of the physical system, several scenarios of ideal glass transition from ergodic to nonergodic behaviour may occur. The validity of the scaling laws for the alpha- and beta-relaxation, originally derived from mode-coupling theory for simple liquids, will be discussed. These predictions will be compared with results from molecular dynamics simulations. We will demonstrate which of the predictions are consistent with these numerical results and which are not. Particular attention will be given to the rotational diffusion tensor.
引用
收藏
页码:6311 / 6322
页数:12
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