Microwave heating as a new way to induce localized enhancements of reaction rate. Non-isothermal and heterogeneous kinetics

被引：127

作者：

Stuerga, D

Gaillard, P

机构：

[1] Lab. Rech. Sur Reactiv. des Solides, Faculté des Sciences Mirande, 21004 Dijon

来源：

TETRAHEDRON | 1996年 / 52卷 / 15期

关键词：

microwave heating; dielectric heating; non-isothermal kinetic; hot spots;

D O I：

10.1016/0040-4020(96)00241-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper we investigate non-isothermal kinetics induced by microwave heating particularly in term of spatial distribution of temperature. We clearly show that it is possible by microwave heating to induce localized superheating (eventually thermal runaway in solid case) which lead to localized reaction rate enhancements. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5505 / 5510

页数：6

共 16 条

[1] APPLICATION OF MICROWAVE-HEATING TECHNIQUES FOR THE SYNTHESIS OF SOLID-STATE INORGANIC-COMPOUNDS
BAGHURST, DR
MINGOS, DMP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (12) : 829 - 830
[2] SYNTHESIS OF 2-ALKYLCYCLOHEXANONES USING SOLVENT-FREE CONDITIONS AND MICROWAVE TECHNOLOGY
BARNIER, JP
LOUPY, A
PIGEON, P
RAMDANI, M
JACQUAULT, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (04): : 397 - 398
[3] BENALLOUM A, 1989, J CHEM SOC CHEM COMM, P386
[4] Berteaud A. J., 1976, Journal of Microwave Power, V11, P315
[5] BOUGRIN K, 1995, NEW J CHEM, V19, P213
[6] ALKYLATION OF POTASSIUM ACETATE IN DRY MEDIA THERMAL-ACTIVATION IN COMMERCIAL MICROWAVE-OVENS
BRAM, G
LOUPY, A
MAJDOUB, M
GUTIERREZ, E
RUIZHITZKY, E
[J]. TETRAHEDRON, 1990, 46 (15) : 5167 - 5176
[7] HERRADON B, 1995, SYNLETT, P455
[8] JACQUAULT P, 1992, Patent No. 4204779
[9] HYDROLYSIS OF ADENOSINE-TRIPHOSPHATE BY CONVENTIONAL OR MICROWAVE-HEATING
JAHNGEN, EGE
LENTZ, RR
PESHECK, PS
SACKETT, PH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (10) : 3406 - 3409
[10] KNIEP R, 1993, ANGEW CHEM INT EDIT, V32, P141

← 1 2 →