Synthesis of chiral 1,3-calix[4](crown-6) ethers as potential mediators for asymmetric recognition processes

被引：36

作者：

Bitter, I ^{[1
]}

Köszegi, É

Grün, A

Bakó, P

Pál, K

Grofcsik, A

Kubinyi, M

Balázs, B

Tóth, G

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem Technol, H-1521 Budapest, Hungary

[2] Budapest Univ Technol & Econ, Dept Phys Chem, H-1521 Budapest, Hungary

[3] Budapest Univ Technol & Econ, Hungarian Acad Sci, Inst Gen & Analyt Chem, Tech Analyt Res Grp, H-1521 Budapest, Hungary

[4] Hungarian Acad Sci, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 08期

基金：

匈牙利科学研究基金会;

关键词：

D O I：

10.1016/S0957-4166(03)00174-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel chromogenic 1,3-calix[4](crown-6) derivatives comprised of 1,1'-binaphthyl-, methyl-alpha-D-glucoside-and D-mannitol moieties in the crown ether ring have been synthesized. UV-vis spectroscopic measurements of the 2,4-dinitrophenylazo chromogenic molecules indicated noticeable chiral discrimination associated with coloration towards primary amine enantiomers. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1025 / 1035

页数：11

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