Charged cyclodextrin derivatives as chiral selectors in capillary electrophoresis

被引：129

作者：

Chankvetadze, B

Endresz, G

Blaschke, G

机构：

[1] Inst. of Pharmaceutical Chemistry, University of Münster, 48149 Münster

[2] Department of Chemistry, Tbilisi State University, 380028, Tbilisi

来源：

CHEMICAL SOCIETY REVIEWS | 1996年 / 25卷 / 02期

关键词：

D O I：

10.1039/cs9962500141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review summarizes recent developments in chiral capillary electrophoresis using charged cyclodextrins as chiral selectors and shows the possibilities of separation of enantiomers of the basic chiral analytes using an extremely low concentration of chiral selector as well as enantioseparation of neutral chiral analytes in capillary electrokinetic chromatography, enantioseparation in counter current flow of chiral selector and solute and several new possibilities for the reversal of enantiomer migration order. The usefulness of NMR spectroscopy is also shown for the better understanding of the mechanism of chiral separation in CE.

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页码：141 / &

页数：14

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