Polyphosphazene-polystyrene copolymers: Block and graft copolymers from polyphosphazene and polystyrene macromonomers

被引:46
作者
Prange, R [1 ]
Reeves, SD [1 ]
Allcock, HR [1 ]
机构
[1] Penn State Univ, Dept Chem, Davey Lab 152, University Pk, PA 16802 USA
关键词
D O I
10.1021/ma000573w
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two methods for the preparation of polyphosphazene-polystyrene copolymers are presented. Both methods permit the production of both di- and triblock copolymers, with controlled molecular weights and narrow polydispersities, and graft copolymers that allow the molecular weight of the polyphosphazene chains and their density along the chain to be controlled.
引用
收藏
页码:5763 / 5765
页数:3
相关论文
共 22 条
[1]   Synthesis of telechelic polyphosphazenes via the ambient temperature living cationic polymerization of amino phosphoranimines [J].
Allcock, HR ;
Nelson, JM ;
Prange, R ;
Crane, CA ;
de Denus, CR .
MACROMOLECULES, 1999, 32 (18) :5736-5743
[2]   Polyphosphazene block copolymers via the controlled cationic, ambient temperature polymerization of phosphoranimines [J].
Allcock, HR ;
Reeves, SD ;
Nelson, JM ;
Crane, CA ;
Manners, I .
MACROMOLECULES, 1997, 30 (07) :2213-2215
[3]   Ambient-temperature direct synthesis of poly(organophosphazenes) via the ''living'' cationic polymerization of organo-substituted phosphoranimines [J].
Allcock, HR ;
Nelson, JM ;
Reeves, SD ;
Honeyman, CH ;
Manners, I .
MACROMOLECULES, 1997, 30 (01) :50-56
[4]  
ALLCOCK HR, 1996, REPORT, V96, P21
[5]  
ALLCOCK HR, UNPUB
[6]  
ALLCOCK HR, 1991, CONTEMPORARY POLYM C
[7]   Amine-terminal polystyrenes: A new strategy for synthesis and new methods for determination of functionality [J].
Cernohous, JJ ;
Macosko, CW ;
Hoye, TR .
MACROMOLECULES, 1998, 31 (12) :3759-3763
[8]  
FRANTA E, 1996, CHEMTECH 0124
[9]   GRAFTING REACTIONS ONTO POLY(ORGANOPHOSPHAZENES) .1. THE CASE OF POLY[BIS(4-ISOPROPYLPHENOXY)PHOSPHAZENE]-G-POLYSTYRENE COPOLYMERS [J].
GLERIA, M ;
BOLOGNESI, A ;
PORZIO, W ;
CATELLANI, M ;
DESTRI, S ;
AUDISIO, G .
MACROMOLECULES, 1987, 20 (03) :469-473
[10]  
Goethals E.J., 1989, Telechelic Polymers: Synthesis and Applications